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Direct observation of o-benzyne formation in photochemical hexadehydro-Diels–Alder (hν-HDDA) reactions

Reactive ortho-benzyne derivatives are believed to be the initial products of liquid-phase [4 + 2]-cycloadditions between a 1,3-diyne and an alkyne via what is known as a hexadehydro-Diels–Alder (HDDA) reaction. The UV/VIS spectroscopic observation of o-benzyne derivatives and their photochemical dy...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Ma, Xiaonan, Maier, Jan, Wenzel, Michael, Friedrich, Alexandra, Steffen, Andreas, Marder, Todd B., Mitrić, Roland, Brixner, Tobias
Formato: Artigo
Idioma:Inglês
Publicado em: The Royal Society of Chemistry 2020
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC8163437/
https://ncbi.nlm.nih.gov/pubmed/34123168
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc03184d
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