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Mechanistic and Kinetic Factors of ortho‐Benzyne Formation in Hexadehydro‐Diels‐Alder (HDDA) Reactions

With the rapid development of the hexadehydro‐Diels‐Alder reaction (HDDA) from its first discovery in 1997, the question of whether a concerted or stepwise mechanism better describes the thermally activated formation of ortho‐benzyne from a diyne and a diynophile has been debated. Mechanistic and ki...

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Bibliografiset tiedot
Julkaisussa:Chemistry
Päätekijät: Maier, Jan, Marder, Todd B.
Aineistotyyppi: Artigo
Kieli:Inglês
Julkaistu: John Wiley and Sons Inc. 2021
Aiheet:
Linkit:https://ncbi.nlm.nih.gov/pmc/articles/PMC8251977/
https://ncbi.nlm.nih.gov/pubmed/33783896
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202100608
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