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The Photochemical Hexadehydro-Diels-Alder (hν-HDDA) Reaction

We demonstrate that the hexadehydro-Diels-Alder cycloisomerization reaction to produce reactive benzyne derivatives can be initiated photochemically. As with the thermal variant of the HDDA process, the reactive intermediates are formed in the absence of reagents or the resulting byproducts required...

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Pubblicato in:J Am Chem Soc
Autori principali: Xu, Feng, Xiao, Xiao, Hoye, Thomas R.
Natura: Artigo
Lingua:Inglês
Pubblicazione: 2017
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC6348472/
https://ncbi.nlm.nih.gov/pubmed/28548500
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.7b03832
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