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The Photochemical Hexadehydro-Diels-Alder (hν-HDDA) Reaction

We demonstrate that the hexadehydro-Diels-Alder cycloisomerization reaction to produce reactive benzyne derivatives can be initiated photochemically. As with the thermal variant of the HDDA process, the reactive intermediates are formed in the absence of reagents or the resulting byproducts required...

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Publicat a:J Am Chem Soc
Autors principals: Xu, Feng, Xiao, Xiao, Hoye, Thomas R.
Format: Artigo
Idioma:Inglês
Publicat: 2017
Matèries:
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC6348472/
https://ncbi.nlm.nih.gov/pubmed/28548500
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.7b03832
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