Vibrational Perturbation of the [FeFe] Hydrogenase H-Cluster Revealed by (13)C(2)H-ADT Labeling

[FeFe] hydrogenases are highly active catalysts for the interconversion of molecular hydrogen with protons and electrons. Here, we use a combination of isotopic labeling, (57)Fe nuclear resonance vibrational spectroscopy (NRVS), and density functional theory (DFT) calculations to observe and charact...

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Publié dans:J Am Chem Soc
Auteurs principaux: Pelmenschikov, Vladimir, Birrell, James A., Gee, Leland B., Richers, Casseday P., Reijerse, Edward J., Wang, Hongxin, Arragain, Simon, Mishra, Nakul, Yoda, Yoshitaka, Matsuura, Hiroaki, Li, Lei, Tamasaku, Kenji, Rauchfuss, Thomas B., Lubitz, Wolfgang, Cramer, Stephen P.
Format: Artigo
Langue:Inglês
Publié: 2021
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Article
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC8211414/
https://ncbi.nlm.nih.gov/pubmed/34043346
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.1c02323
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