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Spectroscopic and Computational Evidence that [FeFe] Hydrogenases Operate Exclusively with CO-Bridged Intermediates
[Image: see text] [FeFe] hydrogenases are extremely active H(2)-converting enzymes. Their mechanism remains highly controversial, in particular, the nature of the one-electron and two-electron reduced intermediates called H(red)H(+) and H(sred)H(+). In one model, the H(red)H(+) and H(sred)H(+) state...
Wedi'i Gadw mewn:
| Cyhoeddwyd yn: | J Am Chem Soc |
|---|---|
| Prif Awduron: | , , , , , , , , , |
| Fformat: | Artigo |
| Iaith: | Inglês |
| Cyhoeddwyd: |
American Chemical Society
2019
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| Mynediad Ar-lein: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6956316/ https://ncbi.nlm.nih.gov/pubmed/31820961 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.9b09745 |
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