Spectroscopic and Computational Evidence that [FeFe] Hydrogenases Operate Exclusively with CO-Bridged Intermediates

[Image: see text] [FeFe] hydrogenases are extremely active H(2)-converting enzymes. Their mechanism remains highly controversial, in particular, the nature of the one-electron and two-electron reduced intermediates called H(red)H(+) and H(sred)H(+). In one model, the H(red)H(+) and H(sred)H(+) state...

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Dettagli Bibliografici
Pubblicato in:J Am Chem Soc
Autori principali: Birrell, James A., Pelmenschikov, Vladimir, Mishra, Nakul, Wang, Hongxin, Yoda, Yoshitaka, Tamasaku, Kenji, Rauchfuss, Thomas B., Cramer, Stephen P., Lubitz, Wolfgang, DeBeer, Serena
Natura: Artigo
Lingua:Inglês
Pubblicazione: American Chemical Society 2019
Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC6956316/
https://ncbi.nlm.nih.gov/pubmed/31820961
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.9b09745
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