Direct Observation of an Iron-Bound Terminal Hydride in [FeFe]-Hydrogenase by Nuclear Resonance Vibrational Spectroscopy

[FeFe]-hydrogenases catalyze the reversible reduction of protons to molecular hydrogen with extremely high efficiency. The active site (“H-cluster”) consists of a [4Fe–4S](H) cluster linked through a bridging cysteine to a [2Fe](H) subsite coordinated by CN(−) and CO ligands featuring a dithiol-amin...

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Publié dans:J Am Chem Soc
Auteurs principaux: Reijerse, Edward J., Pham, Cindy C., Pelmenschikov, Vladimir, Gilbert-Wilson, Ryan, Adamska-Venkatesh, Agnieszka, Siebel, Judith F., Gee, Leland B., Yoda, Yoshitaka, Tamasaku, Kenji, Lubitz, Wolfgang, Rauchfuss, Thomas B., Cramer, Stephen P.
Format: Artigo
Langue:Inglês
Publié: 2017
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Article
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC5545132/
https://ncbi.nlm.nih.gov/pubmed/28291336
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.7b00686
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