Spectroscopic Investigations of [FeFe] Hydrogenase Maturated with [(57)Fe(2)(adt)(CN)(2)(CO)(4)](2–)

The preparation and spectroscopic characterization of a CO-inhibited [FeFe] hydrogenase with a selectively (57)Fe-labeled binuclear subsite is described. The precursor [(57)Fe(2)(adt)(CN)(2)(CO)(4)](2–) was synthesized from the (57)Fe metal, S(8), CO, (NEt(4))CN, NH(4)Cl, and CH(2)O. (Et(4)N)(2)[(57...

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Publicado no:J Am Chem Soc
Main Authors: Gilbert-Wilson, Ryan, Siebel, Judith F., Adamska-Venkatesh, Agnieszka, Pham, Cindy C., Reijerse, Edward, Wang, Hongxin, Cramer, Stephen P., Lubitz, Wolfgang, Rauchfuss, Thomas B.
Formato: Artigo
Idioma:Inglês
Publicado em: 2015
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Article
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4799848/
https://ncbi.nlm.nih.gov/pubmed/26091969
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.5b03270
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