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A [RuRu] Analogue of an [FeFe]-Hydrogenase Traps the Key Hydride Intermediate of the Catalytic Cycle
The active site of the [FeFe]-hydrogenases features a binuclear [2Fe](H) sub-cluster that contains a unique bridging amine moiety close to an exposed iron center. Heterolytic splitting of H(2) results in the formation of a transient terminal hydride at this iron site, which, however is difficult to...
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| Publié dans: | Angew Chem Int Ed Engl |
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| Auteurs principaux: | , , , , |
| Format: | Artigo |
| Langue: | Inglês |
| Publié: |
2018
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| Sujets: | |
| Accès en ligne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5924579/ https://ncbi.nlm.nih.gov/pubmed/29577535 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201801914 |
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