Llwytho...
Hydrogen Atom Abstraction by High-Valent Fe(OH) versus Mn(OH) Porphyrinoid Complexes: Mechanistic Insights from Experimental and Computational Studies
High-valent metal-hydroxide species have been implicated as key intermediates in hydroxylation chemistry catalyzed by heme monooxygenases such as the cytochrome P450s. However, in some classes of P450s, a bifurcation from the typical oxygen rebound pathway is observed, wherein the protonated Fe(rV)(...
Wedi'i Gadw mewn:
| Cyhoeddwyd yn: | Inorg Chem |
|---|---|
| Prif Awduron: | , , , , , |
| Fformat: | Artigo |
| Iaith: | Inglês |
| Cyhoeddwyd: |
2019
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| Pynciau: | |
| Mynediad Ar-lein: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7271964/ https://ncbi.nlm.nih.gov/pubmed/31804814 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.inorgchem.9b02923 |
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