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Strong Inhibition of O-Atom Transfer Reactivity for Mn(IV)(O)(π-radical-cation)(Lewis acid) Versus Mn(V)(O) Porphyrinoid Complexes
The oxygen atom transfer (OAT) reactivity of two valence tautomers of a Mn(V)(O) porphyrinoid complex was compared. The OAT kinetics of Mn(V)(O)(TBP(8)Cz) (TBP(8)Cz = octakis(p-tert-butylphenyl)corrolazinato(3−)) reacting with a series of triarylphosphine (PAr(3)) substrates were monitored by stoppe...
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| Publicado no: | J Am Chem Soc |
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| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2015
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4888055/ https://ncbi.nlm.nih.gov/pubmed/25964988 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.5b00875 |
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