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Mn(V)(O) versus Cr(V)(O) Porphyrinoid Complexes: Structural Characterization and Implications for Basicity Controlling H-Atom Abstraction
Isomorphous crystals of Mn(V)(O) and Cr(V)(O) corrolazines were characterized by single crystal X-ray diffraction. Reactivity studies with H-atom donors and separated PCET reagents show a dramatic difference in H-atom abstracting abilities for these two complexes. The implied large difference in dri...
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| Publicado no: | J Am Chem Soc |
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| Main Authors: | , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2015
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4880368/ https://ncbi.nlm.nih.gov/pubmed/26295412 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.5b05142 |
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