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Mn(V)(O) versus Cr(V)(O) Porphyrinoid Complexes: Structural Characterization and Implications for Basicity Controlling H-Atom Abstraction

Isomorphous crystals of Mn(V)(O) and Cr(V)(O) corrolazines were characterized by single crystal X-ray diffraction. Reactivity studies with H-atom donors and separated PCET reagents show a dramatic difference in H-atom abstracting abilities for these two complexes. The implied large difference in dri...

詳細記述

保存先:
書誌詳細
出版年:J Am Chem Soc
主要な著者: Baglia, Regina A., Prokop-Prigge, Katharine A., Neu, Heather M., Siegler, Maxime A., Goldberg, David P.
フォーマット: Artigo
言語:Inglês
出版事項: 2015
主題:
オンライン・アクセス:https://ncbi.nlm.nih.gov/pmc/articles/PMC4880368/
https://ncbi.nlm.nih.gov/pubmed/26295412
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.5b05142
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