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Light–Driven, Proton–Controlled, Catalytic Aerobic C–H Oxidation Mediated by a Mn(III) Porphyrinoid Complex

The visible light-driven, catalytic aerobic oxidation of benzylic C-H bonds was mediated by an Mn(III) corrolazine complex. To achieve catalytic turnovers, a strict selective requirement for the addition of protons was established. The resting state of the catalyst was unambiguously characterized by...

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Détails bibliographiques
Publié dans:J Am Chem Soc
Auteurs principaux: Neu, Heather M., Jung, Jieun, Baglia, Regina A., Siegler, Maxime A., Ohkubo, Kei, Fukuzumi, Shunichi, Goldberg, David P.
Format: Artigo
Langue:Inglês
Publié: 2015
Sujets:
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC4888065/
https://ncbi.nlm.nih.gov/pubmed/25839905
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.5b00816
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