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Light–Driven, Proton–Controlled, Catalytic Aerobic C–H Oxidation Mediated by a Mn(III) Porphyrinoid Complex
The visible light-driven, catalytic aerobic oxidation of benzylic C-H bonds was mediated by an Mn(III) corrolazine complex. To achieve catalytic turnovers, a strict selective requirement for the addition of protons was established. The resting state of the catalyst was unambiguously characterized by...
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| Publicado no: | J Am Chem Soc |
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| Main Authors: | , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2015
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4888065/ https://ncbi.nlm.nih.gov/pubmed/25839905 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.5b00816 |
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