Photocatalytic Oxygenation of Substrates by Dioxygen with Protonated Manganese(III) Corrolazine

UV-vis spectral titrations of a manganese(III) corrolazine complex [Mn(III)(TBP(8)Cz): TBP(8)Cz = octakis(p-tert-butylphenyl)corrolazinato(3−)] with HOTf in benzonitrile (PhCN) indicate mono- and diprotonation of Mn(III)(TBP(8)Cz) to give Mn(III)(OTf)(TBP(8)Cz(H)) and [Mn(III)(OTf)(H(2)O)(TBP(8)Cz(H...

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Udgivet i:Inorg Chem
Main Authors: Jung, Jieun, Neu, Heather M., Leeladee, Pannee, Siegler, Maxime A., Ohkubo, Kei, Goldberg, David P., Fukuzumi, Shunichi
Format: Artigo
Sprog:Inglês
Udgivet: 2016
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Article
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC4893963/
https://ncbi.nlm.nih.gov/pubmed/26974004
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.inorgchem.5b02019
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