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Lewis Acid-Induced Change from Four- to Two-Electron Reduction of Dioxygen Catalyzed by Copper Complexes Using Scandium Triflate

Mononuclear copper complexes, [(tmpa)Cu(II)(CH(3)CN)](ClO(4))(2) (1, tmpa = tris(2-pyridylmethyl)amine) and [(BzQ)Cu(II)(H(2)O)(2)](ClO(4))(2) (2, BzQ = bis(2-quinolinylmethyl)benzylamine)], act as efficient catalysts for the selective two-electron reduction of O(2) by ferrocene derivatives in the p...

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Detalhes bibliográficos
Publicado no:J Am Chem Soc
Main Authors: Kakuda, Saya, Rolle, Clarence, Ohkubo, Kei, Siegler, Maxime A., Karlin, Kenneth D., Fukuzumi, Shunichi
Formato: Artigo
Idioma:Inglês
Publicado em: 2015
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4630010/
https://ncbi.nlm.nih.gov/pubmed/25659416
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja512584r
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