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Lewis Acid-Induced Change from Four- to Two-Electron Reduction of Dioxygen Catalyzed by Copper Complexes Using Scandium Triflate
Mononuclear copper complexes, [(tmpa)Cu(II)(CH(3)CN)](ClO(4))(2) (1, tmpa = tris(2-pyridylmethyl)amine) and [(BzQ)Cu(II)(H(2)O)(2)](ClO(4))(2) (2, BzQ = bis(2-quinolinylmethyl)benzylamine)], act as efficient catalysts for the selective two-electron reduction of O(2) by ferrocene derivatives in the p...
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| Publicado en: | J Am Chem Soc |
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| Autores principales: | , , , , , |
| Formato: | Artigo |
| Lenguaje: | Inglês |
| Publicado: |
2015
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| Materias: | |
| Acceso en línea: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4630010/ https://ncbi.nlm.nih.gov/pubmed/25659416 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja512584r |
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