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Enhanced Catalytic Four-Electron Dioxygen (O(2)) and Two-Electron Hydrogen Peroxide (H(2)O(2)) Reduction with a Copper(II) Complex Possessing a Pendant Ligand Pivalamido Group
A copper complex, [(PV-tmpa)Cu(II)](ClO(4))(2) (1) [PV-tmpa = bis(pyrid-2-ylmethyl){[6-(pivalamido)pyrid-2-yl]methyl}-amine], acts as a more efficient catalyst for the four-electron reduction of O(2) by decamethylferrocene (Fc*) in the presence of trifluoroacetic acid (CF(3)COOH) in acetone as compa...
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| Main Authors: | , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2013
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3682076/ https://ncbi.nlm.nih.gov/pubmed/23509853 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja3125977 |
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