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Temperature Independent Catalytic Two-Electron Reduction of Dioxygen by Ferrocenes with a Tris[2-(2-pyridyl)ethyl]amine-Copper(II) Catalyst in the Presence of Perchloric Acid
Selective two-electron plus two-proton (2e(−)/2H(+)) reduction of O(2) to hydrogen peroxide by ferrocene (Fc) or 1,1′-dimethylferrocene (Me(2)Fc) in the presence of perchloric acid is catalyzed efficiently by a mononuclear copper(II) complex, [Cu(II)(tepa)](2+) {tepa = tris[2-(2-pyridyl)ethyl]amine}...
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| Main Authors: | , , , , , |
|---|---|
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2013
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3596002/ https://ncbi.nlm.nih.gov/pubmed/23394287 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja312523u |
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