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Factors that Control Catalytic Two- vs Four-Electron Reduction of Dioxygen by Copper Complexes
The selective two-electron reduction of O(2) by one-electron reductants such as decamethylferrocene (Fc(*)) and octamethylferrocene (Me(8)Fc) is efficiently catalyzed by a binuclear Cu(II) complex ([Cu(II)(2)(LO)(OH)](2+) (D1) {LO is a binucleating ligand with copper-bridging phenolate moiety} in th...
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| Main Authors: | , , , , , |
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| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
2012
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| Teme: | |
| Online dostop: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3381452/ https://ncbi.nlm.nih.gov/pubmed/22462521 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja211656g |
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