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Factors that Control Catalytic Two- vs Four-Electron Reduction of Dioxygen by Copper Complexes

The selective two-electron reduction of O(2) by one-electron reductants such as decamethylferrocene (Fc(*)) and octamethylferrocene (Me(8)Fc) is efficiently catalyzed by a binuclear Cu(II) complex ([Cu(II)(2)(LO)(OH)](2+) (D1) {LO is a binucleating ligand with copper-bridging phenolate moiety} in th...

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Hlavní autoři: Fukuzumi, Shunichi, Tahsini, Laleh, Lee, Yong-Min, Ohkubo, Kei, Nam, Wonwoo, Karlin, Kenneth D.
Médium: Artigo
Jazyk:Inglês
Vydáno: 2012
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC3381452/
https://ncbi.nlm.nih.gov/pubmed/22462521
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja211656g
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