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Electron-Transfer Reduction of Dinuclear Copper Peroxo and Bis-μ-oxo Complexes Leading to the Catalytic Four-Electron Reduction of Dioxygen to Water
The four-electron reduction of dioxygen by decamethylferrocene (Fc*) to water is efficiently catalyzed by a binuclear copper(II) complex (1) and a mononuclear copper(II) complex (2) in the presence of trifluoroacetic acid in acetone at 298 K. Fast electron transfer from Fc* to 1 and 2 affords the co...
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| Main Authors: | , , , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2012
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3316124/ https://ncbi.nlm.nih.gov/pubmed/22237962 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201103215 |
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