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Electron-Transfer Reduction of Dinuclear Copper Peroxo and Bis-μ-oxo Complexes Leading to the Catalytic Four-Electron Reduction of Dioxygen to Water

The four-electron reduction of dioxygen by decamethylferrocene (Fc*) to water is efficiently catalyzed by a binuclear copper(II) complex (1) and a mononuclear copper(II) complex (2) in the presence of trifluoroacetic acid in acetone at 298 K. Fast electron transfer from Fc* to 1 and 2 affords the co...

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Autori principali: Tahsini, Laleh, Kotani, Hiroaki, Lee, Yong-Min, Cho, Jaeheung, Nam, Wonwoo, Karlin, Kenneth D., Fukuzumi, Shunichi
Natura: Artigo
Lingua:Inglês
Pubblicazione: 2012
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC3316124/
https://ncbi.nlm.nih.gov/pubmed/22237962
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201103215
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