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Acid-Induced Mechanism Change and Overpotential Decrease in Dioxygen Reduction Catalysis with a Dinuclear Copper Complex
Catalytic four-electron reduction of O(2) by ferrocene (Fc) and 1,1′-dimethylferrocene (Me(2)Fc) occurs efficiently with a dinuclear copper(II) complex [Cu(II)(2)(XYLO)(OH)](2+) (1), where XYLO is a m-xylene-linked bis[(2-(2-pyridyl)ethyl)amine dinucleating ligand with copper-bridging phenolate moie...
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| Main Authors: | , , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2013
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3596431/ https://ncbi.nlm.nih.gov/pubmed/23442145 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja312256u |
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