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Kinetics and thermodynamics of formation and electron-transfer reactions of Cu-O(2) and Cu(2)-O(2) complexes

The kinetics and thermodynamics of formation of Cu(II)-superoxo (Cu-O(2)) complexes by the reaction of Cu(I) complexes with dioxygen (O(2)) and the reduction of Cu(II)-superoxo complexes to dinuclear Cu-peroxo complexes are discussed. In the former case, electron transfer from a Cu(I) complex to O(2...

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Detalhes bibliográficos
Main Authors: Fukuzumi, Shunichi, Karlin, Kenneth D.
Formato: Artigo
Idioma:Inglês
Publicado em: 2012
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3587051/
https://ncbi.nlm.nih.gov/pubmed/23470920
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.ccr.2012.05.031
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