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Laser-Induced Dynamics of Peroxo-Dicopper(II) Complexes Vary with Ligand Architecture; One-Photon Two-Electron O(2)-Ejection and Formation of Mixed-Valent Cu(I)Cu(II)-Superoxide Intermediates

The overall one-photon two-electron peroxide-to-dioxygen oxidation chemistry (O(2)(2−) + 1 hν → O(2) + 2e(−)) was achieved with copper complexes. Interestingly, light excitation of peroxo dinuclear copper(II) complexes with an μ-η(2)-η(2)–(side-on) peroxo ligation was found to release dioxygen while...

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Bibliografske podrobnosti
izdano v:J Am Chem Soc
Main Authors: Saracini, Claudio, Ohkubo, Kei, Suenobu, Tomoyoshi, Meyer, Gerald J., Karlin, Kenneth D., Fukuzumi, Shunichi
Format: Artigo
Jezik:Inglês
Izdano: 2015
Teme:
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC4704693/
https://ncbi.nlm.nih.gov/pubmed/26651492
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.5b10177
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