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Laser-Induced Dynamics of Peroxo-Dicopper(II) Complexes Vary with Ligand Architecture; One-Photon Two-Electron O(2)-Ejection and Formation of Mixed-Valent Cu(I)Cu(II)-Superoxide Intermediates
The overall one-photon two-electron peroxide-to-dioxygen oxidation chemistry (O(2)(2−) + 1 hν → O(2) + 2e(−)) was achieved with copper complexes. Interestingly, light excitation of peroxo dinuclear copper(II) complexes with an μ-η(2)-η(2)–(side-on) peroxo ligation was found to release dioxygen while...
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| Gepubliceerd in: | J Am Chem Soc |
|---|---|
| Hoofdauteurs: | , , , , , |
| Formaat: | Artigo |
| Taal: | Inglês |
| Gepubliceerd in: |
2015
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| Onderwerpen: | |
| Online toegang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4704693/ https://ncbi.nlm.nih.gov/pubmed/26651492 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.5b10177 |
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