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Thioether S-Ligation in a Side-on μ-η(2):η(2)-Peroxo Dicopper(II) Complex
[(ANS)Cu(I)(CH(3)CN)](+) (1A), with N(2)S(thioether) ANS ligand, reacts with O(2) giving a side-on peroxodicopper(II) species [{(ANS)Cu(II)}(2)(μ-η(2):η(2)-O(2)(2−))](2+) (1P), ν(O-O) = 731 cm(−1). 1P is shown to possesses S-thioether ligation, following chemical-spectroscopic comparisons with analo...
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| Main Authors: | , , , , , , |
|---|---|
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2009
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2908150/ https://ncbi.nlm.nih.gov/pubmed/20024303 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/b918616f |
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