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Thioether S-Ligation in a Side-on μ-η(2):η(2)-Peroxo Dicopper(II) Complex

[(ANS)Cu(I)(CH(3)CN)](+) (1A), with N(2)S(thioether) ANS ligand, reacts with O(2) giving a side-on peroxodicopper(II) species [{(ANS)Cu(II)}(2)(μ-η(2):η(2)-O(2)(2−))](2+) (1P), ν(O-O) = 731 cm(−1). 1P is shown to possesses S-thioether ligation, following chemical-spectroscopic comparisons with analo...

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Bibliografiske detaljer
Main Authors: Young Park, Ga, Lee, Yunho, Lee, Dong-Heon, Woertink, Julia S., Sarjeant, Amy A. Narducci, Solomon, Edward I., Karlin, Kenneth D.
Format: Artigo
Sprog:Inglês
Udgivet: 2009
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC2908150/
https://ncbi.nlm.nih.gov/pubmed/20024303
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/b918616f
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