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Geometric and Electronic Structure of [{Cu(MeAN)}(2)(μ-η(2):η(2)(O(2)(2−)))](2+) with an Unusually Long O–O Bond: O–O Bond Weakening vs Activation for Reductive Cleavage

Certain side-on peroxo dicopper(II) species with particularly low υ(O–O) (710–730 cm(−1)) have been found in equilibrium with their bis-μ-oxo dicopper(III) isomer. An issue is whether such side-on peroxo bridges are further activated for O–O cleavage. In a previous study (Liang, H.-C., et al., J. Am...

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Detalhes bibliográficos
Main Authors:	Park, Ga Young, Qayyum, Munzarin F., Woertink, Julia, Hodgson, Keith O., Hedman, Britt, Narducci Sarjeant, Amy A., Solomon, Edward I., Karlin, Kenneth D.
Formato:	Artigo
Idioma:	Inglês
Publicado em:	2012
Assuntos:	Article
Acesso em linha:	https://ncbi.nlm.nih.gov/pmc/articles/PMC3437010/ https://ncbi.nlm.nih.gov/pubmed/22571744 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja300674m
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Geometric and Electronic Structure of [{Cu(MeAN)}(2)(μ-η(2):η(2)(O(2)(2−)))](2+) with an Unusually Long O–O Bond: O–O Bond Weakening vs Activation for Reductive Cleavage

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