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Geometric and Electronic Structure of [{Cu(MeAN)}(2)(μ-η(2):η(2)(O(2)(2−)))](2+) with an Unusually Long O–O Bond: O–O Bond Weakening vs Activation for Reductive Cleavage
Certain side-on peroxo dicopper(II) species with particularly low υ(O–O) (710–730 cm(−1)) have been found in equilibrium with their bis-μ-oxo dicopper(III) isomer. An issue is whether such side-on peroxo bridges are further activated for O–O cleavage. In a previous study (Liang, H.-C., et al., J. Am...
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| Autors principals: | , , , , , , , |
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| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2012
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3437010/ https://ncbi.nlm.nih.gov/pubmed/22571744 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja300674m |
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