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L-edge X-ray Absorption Spectroscopy and DFT Calculations on Cu(2)O(2) Species: Direct Electrophilic Aromatic Attack by Side-on Peroxo Bridged Dicopper(II) Complexes
The hydroxylation of aromatic substrates catalyzed by coupled binuclear copper enzymes has been observed with side-on-peroxo-dicopper(II) (P) and bis-μ-oxo-dicopper(III) (O) model complexes. The substrate-bound-O intermediate in [Cu(II)(2)(DBED)(2)(O)(2)](2+) (DBED=N,N′-di-tert-butyl-ethylenediamine...
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| Asıl Yazarlar: | , , , , , , , |
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| Materyal Türü: | Artigo |
| Dil: | Inglês |
| Baskı/Yayın Bilgisi: |
2013
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| Konular: | |
| Online Erişim: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3891796/ https://ncbi.nlm.nih.gov/pubmed/24102191 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja4078717 |
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