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XAS and DFT Investigation of Mononuclear Cobalt(III)-Peroxo Complexes: Electronic Control of Geometric Structure in CoO(2) versus NiO(2) Systems
The geometric and electronic structures of two mononuclear [(L)CoO(2)](+) complexes, [(12-TMC)CoO(2)](ClO(4)) (1) and [(14-TMC)CoO(2)](ClO(4)) (2), have been evaluated using Co K-edge x-ray absorption spectroscopy (XAS) and extended x-ray absorption fine structure (EXAFS) and correlated with density...
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2010
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3130071/ https://ncbi.nlm.nih.gov/pubmed/21142119 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic101730r |
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