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Mononuclear nickel(II)-superoxo and nickel(III)-peroxo complexes bearing a common macrocyclic TMC ligand

Mononuclear metal-dioxygen adducts, such as metal-superoxo and -peroxo species, are generated as key intermediates in the catalytic cycles of dioxygen activation by heme and non-heme metalloenzymes. We have shown recently that the geometric and electronic structure of the Ni-O(2) core in [Ni(n-TMC)(...

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Main Authors: Cho, Jaeheung, Kang, Hye Yeon, Liu, Lei V., Sarangi, Ritimukta, Solomon, Edward I., Nam, Wonwoo
格式: Artigo
語言:Inglês
出版: 2013
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在線閱讀:https://ncbi.nlm.nih.gov/pmc/articles/PMC3646059/
https://ncbi.nlm.nih.gov/pubmed/23662168
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/C3SC22173C
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