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Synthesis, Characterization, and Reactivity of Cobalt(III)–Oxygen Complexes Bearing a Macrocyclic N-Tetramethylated Cyclam Ligand
Mononuclear metal–dioxygen species are key intermediates that are frequently observed in the catalytic cycles of dioxygen activation by metal-loenzymes and their biomimetic compounds. In this work, a side-on cobalt-(III)–peroxo complex bearing a macro-cyclic N-tetramethylated cyclam (TMC) ligand, [C...
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| Autors principals: | , , , , |
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| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2013
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3928501/ https://ncbi.nlm.nih.gov/pubmed/24038300 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201300107 |
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