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Geometric and Electronic Structure and Reactivity of a Mononuclear “Side-On” Nickel(III)-Peroxo Complex
Metal-O(2) adducts, such as metal-superoxo and -peroxo species, are key intermediates often detected in the catalytic cycles of dioxygen activation by metalloenzymes and biomimetic compounds. The synthesis and spectroscopic characterization of an end-on nickel(II)-superoxo complex with a 14-membered...
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| Main Authors: | , , , , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2009
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2920495/ https://ncbi.nlm.nih.gov/pubmed/20711413 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/nchem.366 |
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