Chromium(IV)–Peroxo Complex Formation and Its Nitric Oxide Dioxygenase Reactivity

The O(2) and NO reactivity of a Cr(II) complex bearing a 12-membered tetraazamacrocyclic TMC ligand, [Cr(II)(12-TMC)(Cl)](+) (1), and the NO reactivity of its peroxo derivative, [Cr(IV)(12-TMC)(O(2))(Cl)](+) (2), are described. By contrast to the previously reported Cr(III)-superoxo complex, [Cr(III...

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Hlavní autoři: Yokoyama, Atsutoshi, Han, Jung Eun, Cho, Jaeheung, Kubo, Minoru, Ogura, Takashi, Siegler, Maxime A., Karlin, Kenneth D., Nam, Wonwoo
Médium: Artigo
Jazyk:Inglês
Vydáno: 2012
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On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC3496875/
https://ncbi.nlm.nih.gov/pubmed/22950528
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja307384e
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