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An isoelectronic NO dioxygenase reaction using a nonheme iron(III)-peroxo complex and nitrosonium ion

Reaction of a nonheme iron(III)-peroxo complex, [Fe(III)(14-TMC)(O(2))](+), with NO(+), a transformation which is essentially isoelectronic with that for nitric oxide dioxygenases [Fe(III)(O(2)(•−)) + NO], affords an iron(IV)-oxo complex, [Fe(IV)(14-TMC)(O)](2+), and nitrogen dioxide (NO(2)), follow...

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Detalhes bibliográficos
Main Authors: Yokoyama, Atsutoshi, Han, Jung Eun, Karlin, Kenneth D., Nam, Wonwoo
Formato: Artigo
Idioma:Inglês
Publicado em: 2014
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4078658/
https://ncbi.nlm.nih.gov/pubmed/24394960
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c3cc48782b
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