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Mechanistic Insight into the Nitric Oxide Dioxygenation Reaction of Nonheme Iron(III)–Superoxo and Manganese(IV)–Peroxo Complexes
Reactions of nonheme Fe(III)–superoxo and Mn(IV)– peroxo complexes bearing a common tetraamido macrocyclic ligand (TAML), namely [(TAML)Fe(III)(O(2))](2−) and [(TAML)Mn(IV)(O(2))](2−), with nitric oxide (NO) afford the Fe(III)–NO(3) complex [(TAML)Fe(III)(NO(3))](2−) and the Mn(V)–oxo complex [(TAML...
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| Publicado no: | Angew Chem Int Ed Engl |
|---|---|
| Main Authors: | , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2016
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5042135/ https://ncbi.nlm.nih.gov/pubmed/27593390 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201605705 |
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