Mechanistic Insight into the Nitric Oxide Dioxygenation Reaction of Nonheme Iron(III)–Superoxo and Manganese(IV)–Peroxo Complexes

Reactions of nonheme Fe(III)–superoxo and Mn(IV)– peroxo complexes bearing a common tetraamido macrocyclic ligand (TAML), namely [(TAML)Fe(III)(O(2))](2−) and [(TAML)Mn(IV)(O(2))](2−), with nitric oxide (NO) afford the Fe(III)–NO(3) complex [(TAML)Fe(III)(NO(3))](2−) and the Mn(V)–oxo complex [(TAML...

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Publicado en:Angew Chem Int Ed Engl
Main Authors: Hong, Seungwoo, Kumar, Pankaj, Cho, Kyung-Bin, Lee, Yong-Min, Karlin, Kenneth D., Nam, Wonwoo
Formato: Artigo
Idioma:Inglês
Publicado: 2016
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Article
Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC5042135/
https://ncbi.nlm.nih.gov/pubmed/27593390
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201605705
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