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XAS and DFT Investigation of Mononuclear Cobalt(III)-Peroxo Complexes: Electronic Control of Geometric Structure in CoO(2) versus NiO(2) Systems

The geometric and electronic structures of two mononuclear [(L)CoO(2)](+) complexes, [(12-TMC)CoO(2)](ClO(4)) (1) and [(14-TMC)CoO(2)](ClO(4)) (2), have been evaluated using Co K-edge x-ray absorption spectroscopy (XAS) and extended x-ray absorption fine structure (EXAFS) and correlated with density...

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Bibliografiske detaljer
Main Authors: Sarangi, Ritimukta, Cho, Jaeheung, Nam, Wonwoo, Solomon, Edward I.
Format: Artigo
Sprog:Inglês
Udgivet: 2010
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC3130071/
https://ncbi.nlm.nih.gov/pubmed/21142119
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic101730r
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