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A Peroxynitrite Dicopper Complex: Formation via Cu–NO and Cu−O(2) Intermediates and Reactivity via O–O Cleavage Chemistry
A mixed-valent Cu(I)Cu(II) complex, [Cu(I,II)(2)-(UN-O(−))](2+) (1), reacts with NO((g)) at −80 °C to form [Cu(I,II)(2)(UN-O(−))(NO)](2+) (2), best described as a mixed-valent nitrosyI complex that has a ν(N−O) band at 1670 cm(−1) in its infrared (IR) spectrum. Complex 2 undertakes a one-electron ox...
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| Veröffentlicht in: | J Am Chem Soc |
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| Hauptverfasser: | , , , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2016
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5293595/ https://ncbi.nlm.nih.gov/pubmed/27960334 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b10689 |
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