Amine Oxidative N-Dealkylation via Cupric Hydroperoxide Cu–OOH Homolytic Cleavage Followed by Site-Specific Fenton Chemistry

Copper(II)-hydroperoxide species are significant intermediates in processes such as fuel cells and (bio)chemical oxidations, all involving stepwise reduction of molecular oxygen. We previously reported a Cu(II)-OOH species that performs oxidative N-dealkylation on a dibenzylamino group that is appen...

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Detalhes bibliográficos
Publicado no:J Am Chem Soc
Main Authors: Kim, Sunghee, Ginsbach, Jake W., Lee, Jung Yoon, Peterson, Ryan L., Liu, Jeffrey J., Siegler, Maxime A., Sarjeant, Amy A., Solomon, Edward I., Karlin, Kenneth D.
Formato: Artigo
Idioma:Inglês
Publicado em: 2015
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Article
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4482616/
https://ncbi.nlm.nih.gov/pubmed/25706825
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja508371q
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