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Intramolecular Hydrogen Bonding Enhances Stability and Reactivity of Mononuclear Cupric Superoxide Complexes
[(L)Cu(II)(O(2)(•−))](+) (i.e., cupric-superoxo) complexes, as the first and/or key reactive intermediates in (bio)chemical Cu-oxidative processes, including in the monooxygenases PHM and DβM, have been systematically stabilized by intramolecular hydrogen bonding within a TMPA ligand-based framework...
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| Vydáno v: | J Am Chem Soc |
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| Hlavní autoři: | , , , , , , |
| Médium: | Artigo |
| Jazyk: | Inglês |
| Vydáno: |
2018
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| Témata: | |
| On-line přístup: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6217813/ https://ncbi.nlm.nih.gov/pubmed/29957998 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.8b04671 |
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