Cargando...
Copper(I) Complex Mediated Nitric Oxide Reductive Coupling: Ligand Hydrogen Bonding Derived Proton Transfer Promotes N(2)O((g)) Release
A cuprous chelate bearing a secondary sphere hydrogen bonding functionality, [(PV-tmpa)Cu(I)](+), transforms (•)NO((g)) to N(2)O((g)) in high-yields in methanol. Ligand derived proton transfer facilitates N–O bond cleavage of a putative hyponitrite intermediate releasing N(2)O((g)), underscoring the...
Guardado en:
| Publicado en: | J Am Chem Soc |
|---|---|
| Autores principales: | , , , |
| Formato: | Artigo |
| Lenguaje: | Inglês |
| Publicado: |
2019
|
| Materias: | |
| Acceso en línea: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6896986/ https://ncbi.nlm.nih.gov/pubmed/31621325 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.9b07286 |
| Etiquetas: |
Agregar Etiqueta
Sin Etiquetas, Sea el primero en etiquetar este registro!
|