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Peroxynitrite Chemistry Derived from Nitric Oxide Reaction with a Cu(II)-OOH Species and a new Copper Mediated NO Reductive Coupling Reaction
New peroxynitrite-copper chemistry ensues via addition of nitric oxide (•NO((g))) to a Cu(II)-hydroperoxo species. In characterizing the system, the ligand-Cu(I) complex was shown to effect •NO((g)) reductive coupling, a new reaction type. Biological implications are discussed.
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2013
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3931255/ https://ncbi.nlm.nih.gov/pubmed/24322625 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c3cc47942k |
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