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Peroxynitrite Chemistry Derived from Nitric Oxide Reaction with a Cu(II)-OOH Species and a new Copper Mediated NO Reductive Coupling Reaction

New peroxynitrite-copper chemistry ensues via addition of nitric oxide (•NO((g))) to a Cu(II)-hydroperoxo species. In characterizing the system, the ligand-Cu(I) complex was shown to effect •NO((g)) reductive coupling, a new reaction type. Biological implications are discussed.

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Bibliografski detalji
Glavni autori: Kim, Sunghee, Siegler, Maxime A., Karlin, Kenneth D.
Format: Artigo
Jezik:Inglês
Izdano: 2013
Teme:
Online pristup:https://ncbi.nlm.nih.gov/pmc/articles/PMC3931255/
https://ncbi.nlm.nih.gov/pubmed/24322625
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c3cc47942k
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