The Stepwise Protonation and Electron-Transfer Reduction of a Primary Copper-Dioxygen Adduct

The protonation-reduction of a dioxygen adduct with [LCu(I)][B(C(6)F(5))(4)], cupric superoxo complex [LCu(II)(O(2)(•−))](+) (1), (L=TMG(3)tren(1,1,1-tris[2-[N(2)-(1,1,3,3-tetramethylguanidino)]ethyl]amine)), has been investigated. Trifluoroacetic acid (HOAc(F)) reversibly associates with the supero...

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Bibliographic Details
Main Authors: Peterson, Ryan L., Ginsbach, Jake W., Cowley, Ryan E., Qayyum, Munzarin F., Himes, Richard A., Siegler, Maxime A., Moore, Cathy D., Hedman, Britt, Hodgson, Keith O., Fukuzumi, Shunichi, Solomon, Edward I., Karlin, Kenneth D.
Format: Artigo
Language:Inglês
Published: 2013
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Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC3874213/
https://ncbi.nlm.nih.gov/pubmed/24164682
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja4065377
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