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Heme-Copper/Dioxygen Complexes: Towards Understanding Ligand-Environmental Effects on Coordination Geometry, Electronic Structure and Reactivity

The nature of the ligand is an important aspect of controlling structure and reactivity in coordination chemistry. In connection with our study of heme/copper/oxygen reactivity relevant to cytochrome c oxidase O(2)-reduction chemistry, we compare the molecular and electronic structure of two high-sp...

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Autors principals: Halime, Zakaria, Kieber-Emmons, Matthew T., Qayyum, Munzarin F., Mondal, Biplab, Puiu, Simona C., Chufán, Eduardo E., Sarjeant, Amy A. N., Hodgson, Keith O., Hedman, Britt, Solomon, Edward I., Karlin, Kenneth D.
Format: Artigo
Idioma:Inglês
Publicat: 2010
Matèries:
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC2893725/
https://ncbi.nlm.nih.gov/pubmed/20380465
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic9020993
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