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Phenol-Induced O–O Bond Cleavage in a Low-Spin Heme–Peroxo–Copper Complex: Implications for O(2) Reduction in Heme–Copper Oxidases
This study evaluates the reaction of a biomimetic heme–peroxo–copper complex, {[(DCHIm)(F(8))-Fe(III)]–(O(2)(2−))–[Cu(II)(AN)]}(+) (1), with a phenolic substrate, involving a net H-atom abstraction to cleave the bridging peroxo O–O bond that produces Fe(IV)=O, Cu(II)—OH, and phenoxyl radical moietie...
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| Udgivet i: | J Am Chem Soc |
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| Main Authors: | , , , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2017
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5605297/ https://ncbi.nlm.nih.gov/pubmed/28521498 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.7b03292 |
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