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Electronic Structure of a Low-spin Heme/Cu Peroxide Complex: Spin-State and Spin-Topology Contributions to Reactivity
This study details the electronic structure of the heme-peroxo-copper adduct {[(F(8))Fe(DCHIm)]-O(2)-[Cu(AN)]}(+) (LS(AN)) in which [Formula: see text] bridges the metals in a μ-1,2 or “end-on” configuration. LS(AN) is generated by addition of coordinating base to the parent complex {[(F(8))Fe]-O(2)...
Gorde:
| Egile Nagusiak: | , , , , |
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| Formatua: | Artigo |
| Hizkuntza: | Inglês |
| Argitaratua: |
2011
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| Gaiak: | |
| Sarrera elektronikoa: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3226806/ https://ncbi.nlm.nih.gov/pubmed/22007669 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic2018727 |
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