ロード中...

Electronic Structure of a Low-spin Heme/Cu Peroxide Complex: Spin-State and Spin-Topology Contributions to Reactivity

This study details the electronic structure of the heme-peroxo-copper adduct {[(F(8))Fe(DCHIm)]-O(2)-[Cu(AN)]}(+) (LS(AN)) in which [Formula: see text] bridges the metals in a μ-1,2 or “end-on” configuration. LS(AN) is generated by addition of coordinating base to the parent complex {[(F(8))Fe]-O(2)...

詳細記述

保存先:
書誌詳細
主要な著者: Kieber-Emmons, Matthew T., Li, Yuqi, Halime, Zakaria, Karlin, Kenneth D., Solomon, Edward I.
フォーマット: Artigo
言語:Inglês
出版事項: 2011
主題:
オンライン・アクセス:https://ncbi.nlm.nih.gov/pmc/articles/PMC3226806/
https://ncbi.nlm.nih.gov/pubmed/22007669
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic2018727
タグ: タグ追加
タグなし, このレコードへの初めてのタグを付けませんか!