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Heme-Copper/Dioxygen Complexes: Towards Understanding Ligand-Environmental Effects on Coordination Geometry, Electronic Structure and Reactivity

The nature of the ligand is an important aspect of controlling structure and reactivity in coordination chemistry. In connection with our study of heme/copper/oxygen reactivity relevant to cytochrome c oxidase O(2)-reduction chemistry, we compare the molecular and electronic structure of two high-sp...

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Detalhes bibliográficos
Main Authors: Halime, Zakaria, Kieber-Emmons, Matthew T., Qayyum, Munzarin F., Mondal, Biplab, Puiu, Simona C., Chufán, Eduardo E., Sarjeant, Amy A. N., Hodgson, Keith O., Hedman, Britt, Solomon, Edward I., Karlin, Kenneth D.
Formato: Artigo
Idioma:Inglês
Publicado em: 2010
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2893725/
https://ncbi.nlm.nih.gov/pubmed/20380465
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic9020993
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