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Peroxo and Superoxo Moieties Bound to Copper Ion: Electron-Transfer Equilibrium with a Small Reorganization Energy
Oxygenation of [Cu(2)(UN-O(−))(DMF)](2+) (1), a structurally characterized dicopper Robin–Day class I mixed-valent Cu(II)Cu(I) complex, with UN-O(−) as a binucleating ligand and where dimethylformamide (DMF) binds to the Cu(II) ion, leads to a superoxo-dicopper(II) species [Cu(II)(2)(UN-O(−))(O(2)(•...
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| Veröffentlicht in: | J Am Chem Soc |
|---|---|
| Hauptverfasser: | , , , , , , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2016
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4950875/ https://ncbi.nlm.nih.gov/pubmed/27228314 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b02404 |
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