Peroxo and Superoxo Moieties Bound to Copper Ion: Electron-Transfer Equilibrium with a Small Reorganization Energy

Oxygenation of [Cu(2)(UN-O(−))(DMF)](2+) (1), a structurally characterized dicopper Robin–Day class I mixed-valent Cu(II)Cu(I) complex, with UN-O(−) as a binucleating ligand and where dimethylformamide (DMF) binds to the Cu(II) ion, leads to a superoxo-dicopper(II) species [Cu(II)(2)(UN-O(−))(O(2)(•...

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Pubblicato in:J Am Chem Soc
Autori principali: Cao, Rui, Saracini, Claudio, Ginsbach, Jake W., Kieber-Emmons, Matthew T., Siegler, Maxime A., Solomon, Edward I., Fukuzumi, Shunichi, Karlin, Kenneth D.
Natura: Artigo
Lingua:Inglês
Pubblicazione: 2016
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Article
Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC4950875/
https://ncbi.nlm.nih.gov/pubmed/27228314
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b02404
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