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Cupric-Superoxo Mediated Inter-Molecular C-H Activation Chemistry
A new cupric-superoxo complex [LCu(II)(O(2)(•−))](+), which possesses particularly strong O–O and Cu–O bonding, is capable of intermolecular C-H activation of the NADH analogue 1-benzyl-1,4-dihydronicotinamide (BNAH). Kinetic studies indicate a first-order dependence on both the Cu-complex and BNAH...
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| Main Authors: | , , , , , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2011
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3091961/ https://ncbi.nlm.nih.gov/pubmed/21265534 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja110466q |
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